Optical Spectra and Chemical Bonding in Transition Metal Complexes: Special Volume II, dedicated to Professor Jørgensen
Axel Christian Klixbüll Jørgensen was a “Polyhistor”,one of the very few in the highly specialized science of our time.His interests and contributions in ch- istry covered the whole Periodic Table.This statement demonstrates the breadth of his interests,however,it also sheds light on the constraints of chemistry which deals with a large, yet limited number of elements. It is not surprising that Jørgensen went beyond these limits,exploring the probable or plausible ch- istry of yet unknown elements and elementary particles such as quarks. Even chemistry itself did not place rigid limits on his mind,he was able to transfer his chemical concepts to scientific problems far beyond the normal such as in astrophysics. “Structure and Bonding” is intimately associated with the name C.K. J- gensen both as initiator and author over several decades.The appearance of a special edition in memory of this great scientist is a self-evident prolongation of his many contributions to the success of this series.
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Spectroscopic Results on Cr3+ Trivalent Transition Metal Ions
G Boulon 1
List of Abbreviations
Ruthenium Complexes of NonInnocent Ligands Aspects of Charge
Contents of Volume
Photoluminescence and Excitation Energy Transfer of Rare Earth Ions
Allowed and Forbidden dd Bands in Octahedral Coordination
Otras ediciones - Ver todas
Optical Spectra and Chemical Bonding in Transition Metal Complexes: Special ...
Vista previa limitada - 2004
absorption atomic band barycentered bond lengths calculated centres charge transfer Chem Phys Lett Chem Soc chromium(III coefficient operators complexes compounds computed corresponding Coulomb coupling covalency Cr3+ crystal d2 configuration decay DEsp diagonal doped electronic emission Eu3+ excited experimental Fe(II function Gütlich Hamiltonian hysteresis Inorg Chem intensity interactions ions iron(II KS-DFT laser Lever ABP LIESST ligand ligand-field theory linewidth lone pair luminescence LUMO magnetic field matrix microstates MLCT molecular orbitals molecules multiplet term Nd3+ nephelauxetic observed obtained optical orthogonal overlap phonon Phys Rev PMT model PMT parameters Qˆ[D Racah parameters repulsion SCS model SCS parameters singlet Slater determinants sol-gel sol-gel glasses spatial species spectra spectral hole-burning spectroscopy spectrum spin basis spin crossover spin orbitals spin singlet spin transition spin triplets structure symmetry Table 24 thermal transition metal triplet two-electron operator values vibronic coupling xerogel xerogel and sol-gel