Optical Spectra and Chemical Bonding in Transition Metal Complexes: Special Volume II, dedicated to Professor JørgensenThomas Schönherr Springer, 2004 M08 19 - 310 páginas Axel Christian Klixbüll Jørgensen was a “Polyhistor”,one of the very few in the highly specialized science of our time.His interests and contributions in ch- istry covered the whole Periodic Table.This statement demonstrates the breadth of his interests,however,it also sheds light on the constraints of chemistry which deals with a large, yet limited number of elements. It is not surprising that Jørgensen went beyond these limits,exploring the probable or plausible ch- istry of yet unknown elements and elementary particles such as quarks. Even chemistry itself did not place rigid limits on his mind,he was able to transfer his chemical concepts to scientific problems far beyond the normal such as in astrophysics. “Structure and Bonding” is intimately associated with the name C.K. J- gensen both as initiator and author over several decades.The appearance of a special edition in memory of this great scientist is a self-evident prolongation of his many contributions to the success of this series. |
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Resultados 1-5 de 52
Página xi
... coupling. In this context he saw that the s.Part of the molecular orbital model that Yamatera had developed for the ligand field of orthoaxial 3d complexes could be applied easily to high-symmetry rare earth systems. This vision of his ...
... coupling. In this context he saw that the s.Part of the molecular orbital model that Yamatera had developed for the ligand field of orthoaxial 3d complexes could be applied easily to high-symmetry rare earth systems. This vision of his ...
Página xiii
... coupling in addressing the subjects of s-d and s-p mixing. The relevance of these orbital interactions had been foreseen by CKJ as early as 1955 and 1971, respectively. The intermixing of s and d was unfortunately introduced in an ...
... coupling in addressing the subjects of s-d and s-p mixing. The relevance of these orbital interactions had been foreseen by CKJ as early as 1955 and 1971, respectively. The intermixing of s and d was unfortunately introduced in an ...
Página xv
... and Vibronic Coupling in Treating s-p and d-s Mixing – a DFT Study D.Reinen,M.Atanasov . . . . . . . . . . . . . . . . . . . . . . . . . . . . 159 Progress in Hole-Burning Spectroscopy of Coordination Compounds H.Riesen ...
... and Vibronic Coupling in Treating s-p and d-s Mixing – a DFT Study D.Reinen,M.Atanasov . . . . . . . . . . . . . . . . . . . . . . . . . . . . 159 Progress in Hole-Burning Spectroscopy of Coordination Compounds H.Riesen ...
Página 14
... coupling. 5 Spectroscopic Results on Cr3+Trivalent Transition Metal Ions Fig. 12 Low temperature emission spectra after excitation at 19,436. 14 G. Boulon Spectroscopic Results on Cr3+ Trivalent Transition Metal Ions Energy Levels of Cr3+ ...
... coupling. 5 Spectroscopic Results on Cr3+Trivalent Transition Metal Ions Fig. 12 Low temperature emission spectra after excitation at 19,436. 14 G. Boulon Spectroscopic Results on Cr3+ Trivalent Transition Metal Ions Energy Levels of Cr3+ ...
Página 15
... coupling and trigonal field which enable the lift of degeneracy into two sublevels 2E(2A–) and 2E(E–). This transition generally gives rise to narrow lines which are called R-lines. 4T2 state arises from the t22e strong field ...
... coupling and trigonal field which enable the lift of degeneracy into two sublevels 2E(2A–) and 2E(E–). This transition generally gives rise to narrow lines which are called R-lines. 4T2 state arises from the t22e strong field ...
Contenido
14 | |
G Boulon 1 | 24 |
List of Abbreviations | 28 |
Ruthenium Complexes of NonInnocent Ligands Aspects of Charge | 77 |
Contents of Volume | 106 |
Photoluminescence and Excitation Energy Transfer of Rare Earth Ions | 115 |
Allowed and Forbidden dd Bands in Octahedral Coordination | 145 |
The Angular Overlap Model and Vibronic Coupling | 159 |
Progress in HoleBurning Spectroscopy of Coordination Compounds | 179 |
in Inorganic Compounds | 180 |
Elucidation of LigandField Theory Reformulation and Revival | 207 |
Author Index Vol 101107 | 303 |
GGG Gadolinium gallium garnet | 308 |
Otras ediciones - Ver todas
Optical Spectra and Chemical Bonding in Transition Metal Complexes: Special ... Thomas Schönherr Vista previa limitada - 2004 |
Optical Spectra and Chemical Bonding in Transition Metal Complexes: Special ... Thomas Schönherr Sin vista previa disponible - 2004 |
Optical Spectra and Chemical Bonding in Transition Metal Complexes: Special ... Thomas Schönherr Sin vista previa disponible - 2004 |
Términos y frases comunes
absorption atomic band barycentered bond lengths calculated centres charge transfer Chem Phys Lett Chem Soc chromium(III coefficient operators complexes compounds computed corresponding Coulomb coupling covalency Cr3+ crystal d2 configuration decay DEsp diagonal doped electronic emission Eu3+ excited experimental Fe(II function Gütlich Hamiltonian hysteresis Inorg Chem intensity interactions ions iron(II KS-DFT laser Lever ABP LIESST ligand ligand-field theory linewidth lone pair luminescence LUMO magnetic field matrix microstates MLCT molecular orbitals molecules multiplet term Nd3+ nephelauxetic observed obtained optical orthogonal overlap phonon Phys Rev PMT model PMT parameters Qˆ[D Racah parameters repulsion SCS model SCS parameters singlet Slater determinants sol-gel sol-gel glasses spatial species spectra spectral hole-burning spectroscopy spectrum spin basis spin crossover spin orbitals spin singlet spin transition spin triplets structure symmetry Table 24 thermal transition metal triplet two-electron operator values vibronic coupling xerogel xerogel and sol-gel