Optical Spectra and Chemical Bonding in Transition Metal Complexes: Special Volume II, dedicated to Professor JørgensenAxel Christian Klixbüll Jørgensen was a “Polyhistor”,one of the very few in the highly specialized science of our time.His interests and contributions in ch- istry covered the whole Periodic Table.This statement demonstrates the breadth of his interests,however,it also sheds light on the constraints of chemistry which deals with a large, yet limited number of elements. It is not surprising that Jørgensen went beyond these limits,exploring the probable or plausible ch- istry of yet unknown elements and elementary particles such as quarks. Even chemistry itself did not place rigid limits on his mind,he was able to transfer his chemical concepts to scientific problems far beyond the normal such as in astrophysics. “Structure and Bonding” is intimately associated with the name C.K. J- gensen both as initiator and author over several decades.The appearance of a special edition in memory of this great scientist is a self-evident prolongation of his many contributions to the success of this series. |
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Página xii
Nolet, Beaulac, Boulanger, and Reber write about intensity borrowing in d-d spectra including the spin-forbidden transitions, subjects to which CKJ made pioneer contributions in 1956. In this context, one cannot help mentioning again ...
Nolet, Beaulac, Boulanger, and Reber write about intensity borrowing in d-d spectra including the spin-forbidden transitions, subjects to which CKJ made pioneer contributions in 1956. In this context, one cannot help mentioning again ...
Página xv
115 Allowed and Forbidden d-d Bands in Octahedral Coordination Compounds: Intensity Borrowing and Interference Dips in Absorption Spectra M.-C.Nolet,R.Beaulac,A.-M.Boulanger,C.Reber .
115 Allowed and Forbidden d-d Bands in Octahedral Coordination Compounds: Intensity Borrowing and Interference Dips in Absorption Spectra M.-C.Nolet,R.Beaulac,A.-M.Boulanger,C.Reber .
Página 7
The emission around 1084 nm is just as intense in s as in p polarization and the s relative intensity increases with the ... Moreover in s-polarization, the emission lines around 1084 and 1093 nm have about the same intensities which ...
The emission around 1084 nm is just as intense in s as in p polarization and the s relative intensity increases with the ... Moreover in s-polarization, the emission lines around 1084 and 1093 nm have about the same intensities which ...
Página 15
We observe in the absorption spectrum (see Fig.2a) two broadbands with maximum intensity at about 15,350 and 20,650 cm–1. The lowest energy band is assigned to a transition 4A2Æ4T2 and is consequently broad. The second broad absorption ...
We observe in the absorption spectrum (see Fig.2a) two broadbands with maximum intensity at about 15,350 and 20,650 cm–1. The lowest energy band is assigned to a transition 4A2Æ4T2 and is consequently broad. The second broad absorption ...
Página 17
For the lines L1 and L2, the maximum position moves towards lower wavenumber whereas the width and the intensity decrease with increasing Xc. The lines L3 and L4 occur only in the emission spectra for crystal with Xc close to the ...
For the lines L1 and L2, the maximum position moves towards lower wavenumber whereas the width and the intensity decrease with increasing Xc. The lines L3 and L4 occur only in the emission spectra for crystal with Xc close to the ...
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Contenido
| 14 | |
G Boulon 1 | 24 |
List of Abbreviations | 28 |
Ruthenium Complexes of NonInnocent Ligands Aspects of Charge | 77 |
Contents of Volume | 106 |
Photoluminescence and Excitation Energy Transfer of Rare Earth Ions | 115 |
Allowed and Forbidden dd Bands in Octahedral Coordination | 145 |
The Angular Overlap Model and Vibronic Coupling | 159 |
Progress in HoleBurning Spectroscopy of Coordination Compounds | 179 |
in Inorganic Compounds | 180 |
Elucidation of LigandField Theory Reformulation and Revival | 207 |
Author Index Vol 101107 | 303 |
GGG Gadolinium gallium garnet | 308 |
Otras ediciones - Ver todas
Optical Spectra and Chemical Bonding in Transition Metal Complexes ..., Volumen2 Thomas Schönherr Vista previa limitada - 2004 |
Optical Spectra and Chemical Bonding in Transition Metal Complexes: Special ... Thomas Schönherr Sin vista previa disponible - 2004 |
Optical Spectra and Chemical Bonding in Transition Metal Complexes: Special ... Thomas Schönherr Sin vista previa disponible - 2004 |
Términos y frases comunes
absorption atomic band barycentered bond lengths calculated centres charge transfer Chem Phys Lett Chem Soc chromium(III coefficient operators complexes compounds computed corresponding Coulomb coupling covalency Cr3+ crystal d2 configuration decay DEsp diagonal doped electronic emission Eu3+ excited experimental Fe(II function Gütlich Hamiltonian hysteresis Inorg Chem intensity interactions ions iron(II KS-DFT laser Lever ABP LIESST ligand ligand-field theory linewidth lone pair luminescence LUMO magnetic field matrix microstates MLCT molecular orbitals molecules multiplet term Nd3+ nephelauxetic observed obtained optical orthogonal overlap phonon Phys Rev PMT model PMT parameters Qˆ[D Racah parameters repulsion SCS model SCS parameters singlet Slater determinants sol-gel sol-gel glasses spatial species spectra spectral hole-burning spectroscopy spectrum spin basis spin crossover spin orbitals spin singlet spin transition spin triplets structure symmetry Table 24 thermal transition metal triplet two-electron operator values vibronic coupling xerogel xerogel and sol-gel
Información bibliográfica
| Título | Optical Spectra and Chemical Bonding in Transition Metal Complexes: Special Volume II, dedicated to Professor Jørgensen Volumen107 de Structure and Bonding |
| Editor | Thomas Schönherr |
| Edición | ilustrada |
| Editor | Springer, 2004 |
| ISBN | 3540365710, 9783540365716 |
| Largo | 310 páginas |
| Exportar cita | BiBTeX EndNote RefMan |