Optical Spectra and Chemical Bonding in Transition Metal Complexes: Special Volume II, dedicated to Professor JørgensenThomas Schönherr Springer, 2004 M08 19 - 310 páginas Axel Christian Klixbüll Jørgensen was a “Polyhistor”,one of the very few in the highly specialized science of our time.His interests and contributions in ch- istry covered the whole Periodic Table.This statement demonstrates the breadth of his interests,however,it also sheds light on the constraints of chemistry which deals with a large, yet limited number of elements. It is not surprising that Jørgensen went beyond these limits,exploring the probable or plausible ch- istry of yet unknown elements and elementary particles such as quarks. Even chemistry itself did not place rigid limits on his mind,he was able to transfer his chemical concepts to scientific problems far beyond the normal such as in astrophysics. “Structure and Bonding” is intimately associated with the name C.K. J- gensen both as initiator and author over several decades.The appearance of a special edition in memory of this great scientist is a self-evident prolongation of his many contributions to the success of this series. |
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Página xi
... symmetry rare earth systems. This vision of his led to the Angular Overlap Model (AOM, 1965). Gütlich, van Koningsbruggen and Renz bring us up to date with the ramifications of the spin cross-over phenomenon, which has its origin in the ...
... symmetry rare earth systems. This vision of his led to the Angular Overlap Model (AOM, 1965). Gütlich, van Koningsbruggen and Renz bring us up to date with the ramifications of the spin cross-over phenomenon, which has its origin in the ...
Página 3
... symmetry and local environment for the Nd3+ ions is essential to be able to account for the gain properties of the Nd3+ laser active centres. In that respect it becomes necessary to know the lattice site occupied by the Nd3+ ions. This ...
... symmetry and local environment for the Nd3+ ions is essential to be able to account for the gain properties of the Nd3+ laser active centres. In that respect it becomes necessary to know the lattice site occupied by the Nd3+ ions. This ...
Página 7
... symmetry (C3) and the. Fig.2 Excitation spectra of a LiNbO3:1%Sc2O3:1%Nd crystal fibre at 12 K by monitoring the total fluorescence intensity from the 4F3/2 excited state Fig. 3 Room temperature polarized absorption spectra of a LiNbO3:1 ...
... symmetry (C3) and the. Fig.2 Excitation spectra of a LiNbO3:1%Sc2O3:1%Nd crystal fibre at 12 K by monitoring the total fluorescence intensity from the 4F3/2 excited state Fig. 3 Room temperature polarized absorption spectra of a LiNbO3:1 ...
Página 8
... symmetry (C3) and the octahedral occupation, three substitution sites are the principal candidates to be occupied by the Nd3+ ions: the Li+ site, the Nb5+ site and the intrinsic free octahedron. These three possible octahedral locations ...
... symmetry (C3) and the octahedral occupation, three substitution sites are the principal candidates to be occupied by the Nd3+ ions: the Li+ site, the Nb5+ site and the intrinsic free octahedron. These three possible octahedral locations ...
Página 9
... symmetry and tetrahedral vacancy. 4. RBS/Channelling. Results. on. Trivalent. RE. Ions. In the RBS spectra (yield vs energy) of our crystals the trivalent RE (RE3+) yield is clearly resolved from that of LiNbO3 (basically due to the Nb sub ...
... symmetry and tetrahedral vacancy. 4. RBS/Channelling. Results. on. Trivalent. RE. Ions. In the RBS spectra (yield vs energy) of our crystals the trivalent RE (RE3+) yield is clearly resolved from that of LiNbO3 (basically due to the Nb sub ...
Contenido
14 | |
G Boulon 1 | 24 |
List of Abbreviations | 28 |
Ruthenium Complexes of NonInnocent Ligands Aspects of Charge | 77 |
Contents of Volume | 106 |
Photoluminescence and Excitation Energy Transfer of Rare Earth Ions | 115 |
Allowed and Forbidden dd Bands in Octahedral Coordination | 145 |
The Angular Overlap Model and Vibronic Coupling | 159 |
Progress in HoleBurning Spectroscopy of Coordination Compounds | 179 |
in Inorganic Compounds | 180 |
Elucidation of LigandField Theory Reformulation and Revival | 207 |
Author Index Vol 101107 | 303 |
GGG Gadolinium gallium garnet | 308 |
Otras ediciones - Ver todas
Optical Spectra and Chemical Bonding in Transition Metal Complexes: Special ... Thomas Schönherr Vista previa limitada - 2004 |
Optical Spectra and Chemical Bonding in Transition Metal Complexes: Special ... Thomas Schönherr Sin vista previa disponible - 2004 |
Optical Spectra and Chemical Bonding in Transition Metal Complexes: Special ... Thomas Schönherr Sin vista previa disponible - 2004 |
Términos y frases comunes
absorption atomic band barycentered bond lengths calculated centres charge transfer Chem Phys Lett Chem Soc chromium(III coefficient operators complexes compounds computed corresponding Coulomb coupling covalency Cr3+ crystal d2 configuration decay DEsp diagonal doped electronic emission Eu3+ excited experimental Fe(II function Gütlich Hamiltonian hysteresis Inorg Chem intensity interactions ions iron(II KS-DFT laser Lever ABP LIESST ligand ligand-field theory linewidth lone pair luminescence LUMO magnetic field matrix microstates MLCT molecular orbitals molecules multiplet term Nd3+ nephelauxetic observed obtained optical orthogonal overlap phonon Phys Rev PMT model PMT parameters Qˆ[D Racah parameters repulsion SCS model SCS parameters singlet Slater determinants sol-gel sol-gel glasses spatial species spectra spectral hole-burning spectroscopy spectrum spin basis spin crossover spin orbitals spin singlet spin transition spin triplets structure symmetry Table 24 thermal transition metal triplet two-electron operator values vibronic coupling xerogel xerogel and sol-gel